Montmorillonite is a 2:1 phyllosilicate clay mineral in the smectite group — the primary component of bentonite and the base mineral for organoclay production.
Montmorillonite (chemical formula: (Na,Ca)₀.₃₃(Al,Mg)₂Si₄O₁₀(OH)₂·nH₂O) is a smectite group clay mineral with a 2:1 layer structure — two tetrahedral silica sheets sandwiching one octahedral alumina sheet. This TOT (tetrahedral-octahedral-tetrahedral) structure allows isomorphic substitution of Al³⁺ by Mg²⁺ in the octahedral layer, creating a permanent negative layer charge that is balanced by exchangeable cations (Na⁺, Ca²⁺, K⁺) in the interlayer space.
Montmorillonite's high cation exchange capacity (CEC: 80–120 meq/100g) and expandable interlayer allow the ion-exchange reaction that converts it to organoclay. The large, flat platelet morphology (aspect ratio 100–300:1) gives organoclay its high surface area and effective gel-forming ability at low treat rates.
| Property | Value |
|---|---|
| Crystal structure | 2:1 TOT phyllosilicate (smectite) |
| Platelet size | 100–300 nm width, 1–2 nm thickness |
| CEC | 80–120 meq/100g |
| Specific surface area | 700–800 m²/g (theoretical) |
| Swelling in water | 15–20× dry volume (Na-form) |
Related: What is Bentonite? · What is Organoclay? · What is Hectorite?
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