What is Montmorillonite?

Montmorillonite is a 2:1 phyllosilicate clay mineral in the smectite group — the primary component of bentonite and the base mineral for organoclay production.

Montmorillonite Definition

Montmorillonite (chemical formula: (Na,Ca)₀.₃₃(Al,Mg)₂Si₄O₁₀(OH)₂·nH₂O) is a smectite group clay mineral with a 2:1 layer structure — two tetrahedral silica sheets sandwiching one octahedral alumina sheet. This TOT (tetrahedral-octahedral-tetrahedral) structure allows isomorphic substitution of Al³⁺ by Mg²⁺ in the octahedral layer, creating a permanent negative layer charge that is balanced by exchangeable cations (Na⁺, Ca²⁺, K⁺) in the interlayer space.

Why Montmorillonite is Used for Organoclay

Montmorillonite's high cation exchange capacity (CEC: 80–120 meq/100g) and expandable interlayer allow the ion-exchange reaction that converts it to organoclay. The large, flat platelet morphology (aspect ratio 100–300:1) gives organoclay its high surface area and effective gel-forming ability at low treat rates.

Key Properties

PropertyValue
Crystal structure2:1 TOT phyllosilicate (smectite)
Platelet size100–300 nm width, 1–2 nm thickness
CEC80–120 meq/100g
Specific surface area700–800 m²/g (theoretical)
Swelling in water15–20× dry volume (Na-form)

Frequently Asked Questions

Is montmorillonite safe?
Montmorillonite (bentonite) is GHS non-hazardous and approved for food processing (E558 in EU), cosmetics, and pharmaceuticals. Organoclay (modified montmorillonite) has the same basic safety profile. Minimize dust exposure during powder handling (P2 mask) — contains ≤3% crystalline silica as a trace mineral component.
What is montmorillonite used for?
Industrial: base mineral for bentonite (WBM viscosifier) and organoclay (rheology modifier for coatings, OBM drilling, greases). Environmental: soil remediation, heavy metal adsorption, clay liners. Consumer: food processing (wine clarification E558), cosmetics (face masks), pharmaceuticals (excipient), animal feed. Civil engineering: slurry walls, tunneling, HDD. What is organoclay →
What is another name for montmorillonite?
Smectite (mineral group); bentonite (commercial clay deposit predominantly montmorillonite); sodium/calcium montmorillonite (by dominant interlayer cation); nanoclay (nanocomposite applications). After quaternary ammonium modification: organoclay, organophilic clay, organobentonite, organic bentonite.

Related: What is Bentonite? · What is Organoclay? · What is Hectorite?

Organoclay from High-Purity Montmorillonite